Poly[[[μ3-5-(pyridine-4-carboxamido)isophthalato]{μ3-5-[(pyridin-1-ium-4-yl)carbonylamino]isophthalato}neodymium(III)] dihydrate]
نویسنده
چکیده
In the title compound, {[Nd(C(14)H(9)N(2)O(5))(C(14)H(8)N(2)O(5))]·2H(2)O}(n), the Nd(III) atom is eight-coordinated as it is surrounded by eight carboxyl-ate O atoms from six ligands in a distorted square-anti-prismatic arrangement. The Nd(III) atoms are linked by HL(-) and L(2-) ligands [H(2)L is 5-(pyridine-4-carboxamido)-isophthalic acid], forming a bilayer network. The layers are linked into a three-demensional network through N-H⋯O and O-H⋯O hydrogen bonds.
منابع مشابه
Poly[[tetraaquatetrakis[μ3-5-(pyridine-4-carboxamido)isophthalato]cobalt(II)dierbium(III)] tetrahydrate]
In the centrosymmetric polymeric title compound, {[CoEr(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Er(III) cation has a coordination number of eight and is surrounded by seven carboxyl-ate O atoms from four 5-(pyridine-4-carboxamido)-isophthalate (L) ligands and one water mol-ecule, forming a distorted square-anti-prismatic arrangement. The Co(II) cation is located on an inversion cent...
متن کاملPoly[[tetraaquatetrakis[μ3-5-(pyridine-4-carboxamido)isophthalato]nickel(II)diterbium(III)] tetrahydrate]
In the title compound, {[NiTb2(C14H8N2O5)4(H2O)4]·4H2O} n , the Tb(III) ion is coordinated by one water mol-ecule and seven O atoms from four 5-(pyridine-4-carboxamido)-isophthalate (L) ligands in a distorted square-anti-prismatic arrangement, while the Ni(II) ion, lying on an inversion center, is six-coordinated in an octa-hedral geometry by two pyridine N atoms, two carboxyl-ate O atoms and t...
متن کاملPoly[[tetraaquatetrakis[μ3-5-(pyridine-4-carboxamido)isophthalato]cobalt(II)diholmium(III)] tetrahydrate]
In the centrosymmetric polymeric title compound, {[CoHo(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Ho(III) ion is coordinated by one water mol-ecule and four 5-(pyridine-4-carboxamido)-isophthalate (L) ligands in a distorted square-anti-prismatic arrangement. The Co(II) ion, located on an inversion center, is coordinated by two pyridine N atoms, two carboxyl-ate O atoms and two water m...
متن کاملPoly[[tetraaquatetrakis[μ3-5-(pyridine-4-carboxamido)isophthalato]cobalt(II)digadolinium(III)] tetrahydrate]
In the centrosymmetric polymeric title compound, {[CoGd(2)(C(14)H(8)N(2)O(5))(4)(H(2)O)(4)]·4H(2)O}(n), the Gd(III) cation is coordinated by one water mol-ecule and four pyridine-4-carboxamido-isophthalate (L) anions in a distorted square-anti-prismatic arrangement, while the Co(II) cation, located on an inversion center, is coordinated by two pyridyl-N atoms, two carboxyl-ate-O atoms and two w...
متن کاملPoly[aqua{μ3-5-[(pyridin-2-ylmethyl)amino]isophthalato-κ5 N,N′:O 1,O 1′:O 3}cobalt(II)]
In the title polymer, {[Co(C(14)H(10)N(2)O(4))(H(2)O)]·3.5H(2)O}(n), the Co(2+) ion is coordinated by three carboxyl-ate O atoms from two 5-[(pyridin-2-ylmeth-yl)amino]-isophthalate anions, two N atoms from a (pyridin-2-ylmeth-yl)amino group and an O atom from a water mol-ecule, furnishing a distorted CoO(4)N(2) octa-hedral geometry. Each anion acts as a μ(3)-bridge, linking cobalt ions into a ...
متن کامل